3-{(E)-[(4-Formylphenyl)iminiumyl]methyl}naphthalen-2-olate
نویسندگان
چکیده
The title Schiff base compound, C(18)H(13)NO(2), is a zwitterion, with the naphthol hy-droxy group deprotonated and the imine N atom protonated. It adopts an E configuration about the central C=N double bond. The dihedral angle between the naphthyl ring system and the benzene ring is 1.73 (11)°. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, adjacent mol-ecules are connected by inter-molecular C-H⋯O hydrogen bonds, forming a supra-molecular ribbon along the b axis.
منابع مشابه
Zwitterionic 1-{(E)-[(2-methylphenyl)iminiumyl]methyl}naphthalen-2-olate
The title Schiff base, C18H15NO, crystallizes in its zwitterionic form and an N-H⋯O hydrogen bond closes an S(6) ring. The dihedral angle between the aromatic ring systems is 36.91 (10)°. Weak aromatic π-π stacking occurs in the crystal [minimum centroid-centroid separation = 3.7771 (15) Å].
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